前苏联专利SU1447273A3 Method of producing manganese sulfate solution

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专利摘要:
A process for the preparation of manganese sulfate solutions having reduced levels of potassium impurity comprising blending a reduced manganese ore, an added source of water soluble aluminum ions and an aqueous acid solution to form a digestion mixture, digesting said mixture, preferably in the presence of crystals of a complex potassium-aluminum salt to form a mixed reaction product containing a liquid phase of manganese sulfate solution and recovering the liquid phase of manganese sulfate solution from said mixed reaction product.
公开号:SU1447273A3
申请号:SU843801011
申请日:1984-10-15
公开日:1988-12-23
发明作者:С.Лафлин Вильям；Дж.Барзак Вирджил；Д.Бауэрман Поль；А.Радо Теодор
申请人:Керр Макджи Кемикал Корпорейшн (Фирма)；
IPC主号:

专利说明:

cm
This invention relates to a process for preparing a manganese sulphate solution used to produce electrolytic manganese dioxide.
The presence of potassium impurity in electrolytic manganese dioxide has an adverse effect when used as a demodulator in the bauar of dry cells, and therefore, a solution of manganese sulphate from which MpO is obtained is raised in potassium content. .
The purpose of the invention is to simplify the process of obtaining MnSO from reduced potassium containing manganese ore.
The method is carried out as follows.
The original ore is reduced by heat treatment at AOO-1200 C in the presence of a reducing agent. At the same time, all manganese (IV) compounds are converted to Mn (II).
After grinding, the reduced ore is mixed with the treated electrolyte containing free sulfuric acid and manganese ions in the presence of a water soluble aluminum salt, taken in an amount of 4.6-9.2 G / l, and a solid phase recycled from the leaching stage in the amount of 13- g / l.
The resulting mixture with a pH of 4.5-6.3 is subjected to leaching at 70-90 ° C for 1-3 hours. Under these conditions, the potassium compound contained in the original ore reacts with aluminum ions to form a complex salt of the formula - (. OE) f. After leaching, the resulting solution of manganese sulphate is separated from the solid phase containing the complex potassium-aluminum salt and undissolved ore. A part of the solid phase is recycled to the stage of mixing the ore with the electrolyte, and the .MnSO solution is further purified from impurities of heavy metals before feeding it into the electrolyzer.
The results of experiments 1-7 are presented in table. 1. The stock solution used in the sample of examples contains 40 g / l of manganese (II) ions, 200 mg / l of potassium ions and 3.0 Mjr / l of iron ions. The solution is divided into seven equal parts of approximately 300 ml and to each part with stirring and
with
0
five
0
five
0
50

0
aluminum sulfate is added to heating, and 13 g / l of potassium-aluminum complex salt is added to some solutions,
As the data in Table 1 show, the use of water-soluble aluminum ions significantly reduces the content of potassium impurities in the manganese leach solution only at a pH of 4.0. In addition, the data show that the rate and extent of removal of potassium impurities increase if the alkaline solution containing water-soluble aluminum ions is heated in contact with crystals of the potassium salt-aluminum.
The second series of experiments was carried out using the same equipment and according to the method used
in examples 1-7. However, the top solution, prepared for the second series of experiments, contains 36 g / l manganese, in the form of manganese (II) ions, 280 mg / l potassium and 6 mg / l iron in the form of iron ions, the pH of the leach solution is 6.3. In all the experiments of the second series, the same crystals of the potassium-aluminum salt by-product were used as in Examples 1-7, the number of crystals being different in each experiment. Different amounts of aluminum sulfate are also added to each experimental solution. Working conditions and reg .. results obtained in the second series of experiments are given in table. 2
As the data of Table 2 show, the operating conditions, the concentration of crystals and the concentration of water-soluble aluminum ions can vary over a wide range. In addition, a change in these conditions has an effect on the rate and extent of removal of potassium impurities from the manganese alkalizing solution over time.
The proposed method, in comparison with the known one, while maintaining the degree of purification from potassium, simplifies the process by reducing the number of operations at the leaching stage and carrying out it under milder conditions, i.e. in a less acidic environment (pH 4.5-6.3 vs. 1-2 according to the known).

权利要求:
Claims (1)
[1]
Invention Formula
The method of obtaining a solution of manganese sulfate used in the production of electrolytic dioxide
. 144 manganese from manganese copper-containing ore, including the reduction of the latter, mixing the reduced ore with the spent electrolyte containing sulfuric acid and manganese ions in the presence of a water-soluble trivalent metal salt, leaching the resulting mixture at 70-90 Cu separation of the resulting manganese sulfate solution from the solid a phase containing undissolved ore and the resulting complex potassium salt, characterized in that, in order to simplify the process, the stage of mixing the ore with the electrolyte as whether a trivalent metal is injected with a water-soluble aluminum salt in the amount of 4.6-9.2 g / l and the solid phase from the leaching stage, recycled in the amount of 13-30 g / l, and mixing is carried out until the pH reaches 4.5-6.3 .
Table 1
Method parameters
Performance indicators
iZIZZZiZQZini
Temperature with
ph
90
50
50
90
90
90
50
2.5 2.5 4.5 4.5. 6.3 6.3 6.3
Potassium-aluminum salt
Not
The concentration of potassium ions, mg / l, with duration, h
Temperature, C
Salt by-product, g / l
Aluminum concentration, g / l
50
90
90
90
50
Yes,
Yes
Yes
Not
Yes
90
90
90
90
20
thirty
13
13
9.2 9.2 9.2 4.6 2.3

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同族专利:

公开号 | 公开日

JPS60166230A|1985-08-29|

DE3437859A1|1985-08-14|

JPS6236970B2|1987-08-10|

GR80663B|1985-06-13|

US4483828A|1984-11-20|

BR8405199A|1986-05-13|

ES536793A0|1985-10-16|

ZA847285B|1985-04-24|

ES8600725A1|1985-10-16|

DE3437859C2|1986-10-02|

引用文献:

公开号 | 申请日 | 公开日 | 申请人 | 专利标题

US1279110A|1918-02-02|1918-09-17|Haslup & Peacock Inc|Process of producing manganese sulfate.|

US3227520A|1962-01-30|1966-01-04|E J Lavino & Co|Production of manganese sulfate solution|

US3667906A|1969-05-15|1972-06-06|Tekkosha Co|Method for producing manganese dioxide containing less potassium|

SU393341A1|1971-07-16|1973-08-10|Проектный , научно исследовательский институт Гипроникель|METHOD OF PROCESSING OF MANGANESE RAW|

US3864118A|1973-02-07|1975-02-04|Bethlehem Steel Corp|Method for producing manganese oxide pellets|

US4285913A|1980-04-25|1981-08-25|Union Carbide Corporation|Process of making manganous sulphate solution with low level impurity of potassium for manufacture of electrolytic manganese dioxide|

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US6156283A|1998-03-23|2000-12-05|Engelhard Corporation|Hydrophobic catalytic materials and method of forming the same|

US6214198B1|1998-12-21|2001-04-10|Kerr-Mcgee Chemical Llc|Method of producing high discharge capacity electrolytic manganese dioxide|

CN102923738A|2012-11-15|2013-02-13|吉首大学|Method for recovering water soluble manganese and magnesium from electrolytic manganese residue|

法律状态:

优先权:

申请号 | 申请日 | 专利标题

US06/577,995|US4483828A|1984-02-08|1984-02-08|Method of producing manganese sulfate solutions of improved purity|

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